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Each enantiomeric pair is racemic – i.e. Insects that come in contact with the direct spray or dried residual of Cyper TC suffer from hyperexcitation of the central nervous system, causing paralysis and eventual death. Slightly more water may be used as long as the amount of product applied per area is the same. %PDF-1.7 %�� mixing ratios of 80:20 and 85:15 of methanol and water, respectively, were able to provide b etter resolution of all peaks. ?�4��g?�d��|�Ȋ%��x=/XK��d]T��-��Ʒ�uei�(Yd��M��{Ƥ��SVmR��f�r>{�O��S�eZ�*�s�ċ��!/�|İ��E��|��SJ�#w�f˻�Y�qZ��I�X��O��h�c hčw��Uʇ��g3��N� ��|X,qE�OSW�V��S]�Ĭ|Z��oXQ];�Z6�}��M�R�`p-m̠wE(��i��A}zR��Հչ)�6��e��^�oqT�� �3k��M>�b\A�:Z��5A��`��R�� )Е)}�V~�â��$۔�ѝ�im?t 4�r�a>}��H3�ˣ�� Use higher rate when populations are high. Such comparison is valid assuming that cypermethrin quantum yield does not vary significantly over the range of 280–305 nm. Add this to the spray tank while agitating the mixture. Stir the solution carefully with a flat paddle (stirrer) and avoid splashing. Put a small amount of water into the bucket first. Material Safety Data Sheets. For lawn treatment, apply 0.4 to 0.8 fluid ounces of permethrin for every 1,000 square feet. �499��ű�",�bBX24J�a��ˤ�11SB��-Ʀ�%�F)Aý%�0��Ċ,L�$4Hi&ub��! H��SMo�0��Q`ْ��(��Y��Z��m^�&V'��#�mE�� 3�㓙O��>6�gg�$�f� Mix water and concentrate in a large clean container, such as a 10 L bucket. The shelf life of the container is 3 years from the date of purchase if stored away from extreme temperatures. Using the application rate stated in the instructions, calculate the amount of pesticide concentrate needed for the size of the area to be sprayed. In the studies submitted for evaluation the cis:trans ratio was in the range of 48:52 to 50:50. Apply 5L of diluted spray mix/100m2up to … COMPOSITION Active Ingredient Cypermethrin (pyrethroid) - 200g/ℓ Cyper TC can be applied at various mix rates depending on the targeted pest and application method. Liquid pesticide sprayers must apply the proper amount of a carefully mixed spray solution to be effective in controlling weed and insect pests. Figure-4 . This Material Requires Further Mixing Before Use ' per gallon of water (0.25%) to treat 1,000 square feet. The application rate of a particular pesticide is the amount of mixed pesticide solution (chemical plus water) which is needed to treat an area of a particular size. Emulsiﬁable concentrate An emulsiﬁable concentrate consists of a solvent and an emulsifying agent in which the insecticide is dissolved. Work out the area to be sprayed. *Cis/Trans ratio: 45/55 + 10 1Synthetic pyrethroid Cypermethrin Insecticide in Water Soluble Packets See Inside Booklet for Additional Precautionary Statements and Directions for Use. Dig the trench and apply 4 gallons of finished solution per 10 linear feet. Ivy leaf roller NSW,WA only Each enantiomeric pair is racemic – i.e. Read the label and put on the appropriate protective equipment as indicated. Calculate how much water is needed to dilute the pesticide to the correct strength. For general use outdoors or as a barrier treatment, use between a 0.1% to 0.25% dilution, which is 0.51 fl. The ISO common name zeta-cypermethrin designates a pyrethroid that can be considered as esterification product of the (S)-α-cyano-3-phenoxybenzyl alcohol and permethric acid. (�(L�ay��`��t��c��4�%?|��މ��b/t�x�&��i�Q�F��ξ�E�#T��R��.6ڨw�Ӟ1�#�Z_-2�� This container and any measuring cups must be used only for this purpose. The residue in milk was 90% extractable and shown to be Cypermethrin. Below are the documents that contain all the technical information on the potential hazards (health, fire, reactivity and environmental) and how to … See Table 1.2 and 1.3 and Fig. See Table 1.2 F2700 Zeta-Cypermethrin Technical InsectiCide Philadel hia, PA 19103 ... 'Cis/trans isomer ratio: Max 75% (±) cis and Min. 50:50 mix of each enantiomer. It will be used to make improvements to this website. ft.. Rc�~8��/n� M�"�_�N~<7��v�ZCe�}�8~�� The isomeric ratio was found to be 1 : 1 cis/trans in both animal matrices. Cypermethrin 25.3%: Chemical Type: Pyrethroid: Formulation: Emulsifiable Concentrate (EC) Mix Rate: For general purpose applications made with a handheld pump sprayer, mix 0.5 to 1.0 ounce of Martin's Viper Insecticide with 1 gallon of water. Cypermethrin insecticide is the active ingredient in Cyper WP, Demon WP, Demon EC, Cynoff EC, Cynoff WP and Cypermethrin EC 4 ounce. oz. 8146 0 obj <>stream 1.1 below. • Half fill the spray tank with clean water. When they are not being used they should be stored safely in the equipment shed. Retreatment oz. This may be the area of a floor or the combined areas of skirting boards or the combined area of external (outside) building foundations. Cypermethrin isomer ratio 40% ≤ cis isomers ≤ 60% The Cypermethrin molecule has 3 chiral centres giving rise to 8 stereoisomers, four pairs of enantiomers – two cis (CIS 1 & CIS 2) and two trans (TRANS 1 & TRANS 2). h�ĕmO�0ǿ�_n/�ώ Uj)� !Z�i��J�4EM`��w��i� To treat turf grass against ants, crickets and grasshoppers, for example, mix 1/2 oz. Cypermethrin cis:trans isomer ratio 40(±5) :60(±5). Divide 32 ounces by 6 (1 part Maintenance treatment and light infestations: 5 mL in 1 L water For crawling insects, apply as a coarse low pressure spray to areas where pests frequent. material and 750 g of the pure insecticide. Termite Pest Control: Mix 1.3-2.6 oz of Cyper TC(5.6 oz for high usage). For flying insects, apply as a surface treatment using a fine spray to wet the surface. Mix 3.2 fl. Work out the area to be sprayed. i��C��g�h~V�]D�}V�_/��[��Q`�w�� endstream endobj startxref Mix 5 g powder with 5 L water to cover 20 square metres (20 m2) Use 1 packet of powder per 10 L water. KOMBAT CYPERMETHRIN Registration No. For example, you want to make a quart bottle diluted at 1-to-5. The cypermethrin molecule has 3 chiral centers giving rise to 8 stereoisomers, four pairs of enantiomers – two cis (CIS I & CIS II) and two trans (TRANS I & TRANS II). Always work in the open and avoid breathing the fumes. To calculate a dilution ratio that is not listed, divide the number of ounces you are wanting to make by the sum of the two numbers in the ratio. Depending on the manufacturing source, the cis:trans ratio varies from 40:60 to 80:20. p��}^�6!�j�m��v��7ۯ�RC��s�^��{��9+� ��(�J For low volume spray equipment use L/ha rate. They should be clearly labelled ‘DANGER - POISON: DO NOT TOUCH’. *k�G��Dt�.mG��ڮ��.�k{_-uё�,[��y��r�r��`��}��W��dG�8IP��G�z��/��S��nd�WY�g��'9{�7��˝��0�(�P�Y4��[OZ�! Fendona® is a fast-acting pyrethroid insecticide that quickly and effectively eliminates disease-causing insects. endstream endobj 8124 0 obj <>stream (If you want to reduce foaming when mixing, see helpful hint at the bottom. L7014 – ACT 36 OF 1947 KOMBAT CYPERMETHRIN is an emulsifiable concentrate contact and stomach insecticide for agricultural use on crops as indicated. Radioactive residue in fat that was removed by solvent extraction was 98%; in addition, 90% of the fat residue was shown to be the parent Cypermethrin. Both cisand transisomers were present. Mixtures of methanol and water with mixing ratios of 80:20 and 85:15 of methanol and water, respectively, were able to provide better resolution of all peaks. Step 2 Dilute Permethrin 10 percent with the correct amount of water. 1 or 2 L 50 or 100 mL 7 days Use this rate in tank mix with 1L/ha (500mL/100L of water) of dichlorvos (500 g/L). 0 Thank you for taking the time to provide feedback. Use) solution. Depending upon the type of pesticide it may be appropriate to wear a respirator. endstream endobj 8121 0 obj <>/Metadata 268 0 R/Pages 8118 0 R/StructTreeRoot 383 0 R/Type/Catalog/ViewerPreferences 8134 0 R>> endobj 8122 0 obj <>/MediaBox[0 0 595.32 841.92]/Parent 8118 0 R/Resources<>/Font<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI]>>/Rotate 0/StructParents 0/Tabs/S/Type/Page>> endobj 8123 0 obj <>stream Cypermethrin consists of eight isomers, four cis and four trans isomers, the cis isomers being the more biologically active. h��S�K�Q?�{��߶}us3�[ؾ��Z��1��朋��f`kH�)d�2b� ��ä��BT�=ԃ��5!� "'�u7��:��9��s�{�� h �9��R�bZ��(�S�r��Z��_�'�Dg�!��F�j~��{ �!�rY�GN��f7�3��H#|�4��k��wŲ�9��3!Yq�~W�f��t]HX�] Ŏ!c��"��W�;�!�a�&rw��j�q{��*�w�ݭo�+��{�&��_>�Ջ�i�ʙ��>�_Q|ѮP� ŧx��&�W��{1��,��]��zC:/�?�.��>�>��>��#\��SW:\��&�@ҕ~�λ��2�]��Ǥ��*f�8J��fL�3ai|&��.1*��ʉ�RR#Ť�@��8l ��MQt��ɡAE��UQ ��)ФX�$��B jJU�`�\9�y|�5Ԇ�K��Ђ�H��xЏ�[��k��=bV��`��h��8m(�/�8�N��S y��M�� yR��ɽ��s},u_��+��E��k��Օ��)��P��1�` b�� oz. Fill the spray tank while maintaining agitation, to ensure thorough mixing of … Comments will be used to improve web content and will not be responded to. Cypermethrin is a synthetic pyrethroid, a man-made active ingredient made to mimic the chemical properties of naturally occurring pyrethrins. to 1.3 fl. States may have more restrictive requirements regarding qualifications of persons using this product. ��}+n/_��A�5ϤcO\Vl"�J��. ��i��ti2��$� �C��&�,@�-��*�� i�~B�卅�,�!r��4�e��&s�v�&'�;-d�} =�k�uR��V��6 %%EOF 8132 0 obj <>/Filter/FlateDecode/ID[<77228E587FD55F4188BF000FE219A116><61296E9A5E71374DB066632849CA3D40>]/Index[8120 27]/Info 8119 0 R/Length 70/Prev 1433116/Root 8121 0 R/Size 8147/Type/XRef/W[1 2 1]>>stream In the case of cypermethrin, the relative importance of an esterase attack as opposed to an oxidative one is more important than for permethrin; for trans-cypermethrin the ratio is 93.2% to 17.3% and for cis-cypermethrin 41.5% to 37.6% in the mouse system. Optimization of mobile phase composition for optimum separation of diastereomers of cypermethrin (CYP), resmethrin (RES) and permethrin (PER), on an achiral Check the pesticide label to find the application rate at which the concentrate should be used. Place the required amount of pesticide into the water. Aboriginal and Torres Strait Islander Health, Environmental Health Practitioner Manual: A resource manual for Environmental Health Practitioners working with Aboriginal and Torres Strait Islander Communities, 6 Stopping the spread of germs and parasites, 10 Effluent disposal drains (leach and French drains), 12 Communities without a sewage disposal system, 5 House cleaning—tidying and maintaining the yard, Chapter 4 Rubbish storage, collection and disposal and environmental management, 8 Setting up a community rubbish collection system, 12 Environmental management—area beautification, 4 Environmental conditions which encourage pests, 7 Types of pesticides and how they enter animals and plants, 9 Protective clothing and equipment (personal protective equipment), 10 Calculating and mixing the correct amount of chemical, 11 Disposal of unused pesticide and empty pesticide containers, 12 Decontamination and maintenance of pesticide application equipment, 13 Safe storage of pesticides and spray equipment, 16 First aid procedures for pesticide poisoning, 4 W ater supply contaminants and disinfection, Chapter 7 Environmental health program management and community education, 2 Starting and managing environmental health work, 3 Planning the environmental health program, 8 Maintenance and storage of equipment and tools, 9 Community environmental health education. SPECIMEN Page 1 of 12 Cyper TC Insecticide For use by individuals/firms licensed or registered by the state to apply termiticide products. Use 10 ml concentrate per 5 L water to cover 40 square metres (40 m2), Mix 5 g powder with 5 L water to cover 20 square metres (20 m2). 8120 0 obj <> endobj Apply at first sign of pest activity before larvae move to fruit. This may be the area of a floor or the combined areas of skirting boards or the combined area of external (outside) building foundations. per gallon of water to treat about 1,000 sq. Permethrin 10 percent with 3 gallons water to treat 1,000 square feet. Whereas cypermethrin refers to a racemic mixture of the alcohol and acid moiety, zeta-cypermethrin is enriched with the -alcohol and has a cis/transS ratio of 45.55 in the 50:50 mix of each enantiomer. In the outdoor photolysis experiments cypermethrin thin film samples under synthetic atmosphere of dry nitrogen and oxygen (4:1 mixing ratio) showed 70% degradation after 4 days. 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